A Lecturer from the Department of Chemistry Publishes a Scientific Research on the Preparation and Characterization of some Metal Complexes with 2,6-Di(((1-octyl-1,2,3-triazole-4-yl)methoxy)methyl)Pyridine and the Study of its Biological Activities

Publishing a Scientific Research

The lecturer from the Department of Chemistry (Lect.. Jahan Hamid Abdul-Amir) published a paper entitled (Preparation and identification of some metallic complexes with 2,6-dioe (((1-octyl-1,2,3-triazole-4-yl)methoxy)methyl)pyridine. And the study of their biological activities in an international journal within the Escobas and Clarify containers (Journal of Eurasian Chemical Communication).
In this paper, the reaction of chelation between 2,6-bis((1-octyl-1H-1,2,3-triazole-4 yl)methoxy)methyl)pyridine organocallicand with metal ions Mn+2 and Pd+2 and Au+3 to form various new complexes. The organic ligand was synthesized using the click reaction between azidooctane and 2,6-bis((prop-2-in-1-acyloxy) methyl) pyridine-1 derivative of triazole, the said reaction was catalyzed by Cu(I). All these new compounds were diagnosed by solid state and solution spectroscopy methods such as 1HNMR, 13CNMR, Uv-Vis, FTIR, mass spectrometry, metal and elemental analyses, magnetic sensitivity, and electrical conductivity at room temperature. Through diagnostics, we concluded that the ligand may act as a tetragonal and pentagonal chelator. Whereas, the L-Pd and L-Au complexes have a square planar geometric shape, while the L-Mn complexes are octahedral. All prepared compounds were applied to selected microorganisms and the ability of these compounds to inhibit the growth of Staph bacteria was tested. aureus, E. coli, and Cand fungi. and Albicans, using three different concentrations (10, 50, and 200) ppm. In general, the results showed that the increase in the concentration gives greater antibacterial and antifungal activity and that the gold compound was more effective than the others, but in particular, the compounds act as a strong antibacterial toward E. coli.